create xml file from sql script

Declare @xmlDoc xml
SET @xmlDoc = (SELECT * FROM USERS AS UserTable For XML AUTO, ELEMENTS, ROOT('Root'))
SELECT @xmlDoc
Result as below : 
<Root>
  <UserTable>
    <UserDBID>1</UserDBID>
    <UserID>Admin                           </UserID>
    <UserName>admin</UserName>
    <Password>49CE5FB6D05148ACB66A</Password>
    <FullName />
    <LocalFullName />
    <Title />
    <Department />
    <UserRole>Administrator</UserRole>
    <IsFirstLogin>0</IsFirstLogin>
    <PwdNeverExpire>1</PwdNeverExpire>
    <PwdLastModifyTime>2013-07-10T13:40:48.470</PwdLastModifyTime>
  </UserTable>
  <UserTable>
    <UserDBID>2</UserDBID>
    <UserID>cshsvc                          </UserID>
    <UserName>cshsvc</UserName>
    <Password>54C0FCD2B54CCE8BE6AD</Password>
    <FullName />
    <LocalFullName />
    <Title />
    <Department />
    <UserRole>Administrator</UserRole>
    <IsFirstLogin>0</IsFirstLogin>
    <PwdNeverExpire>1</PwdNeverExpire>
    <PwdLastModifyTime>2013-07-10T13:38:25.070</PwdLastModifyTime>
  </UserTable>
</Root>
SelectEmp_Id,Emp_Namefrom tblEmployee WhereEmp_Id<3For XML AUTO,ELEMENTS
--For XML [MODE],ELEMENTS

MODE

AUTO, RAW, EXPLICIT

Result [AUTO]

<tblEmployee><Emp_Id>1</Emp_Id><Emp_Name>AAA</Emp_Name></tblEmployee><tblEmployee><Emp_Id>2</Emp_Id><Emp_Name>BBB</Emp_Name></tblEmployee>

Result [RAW]

Above Xml with Instead of <tblEmployee> here..... <ROW> and </tblEmployee> is </ROW>

SELECT ( SELECT 'White' AS Color1,
'Blue' AS Color2,
'Black' AS Color3,
'Light' AS 'Color4/@Special',
'Green' AS Color4,
'Red' AS Color5
FOR
XML PATH('Colors'),
TYPE
),
 ( SELECT 'Apple' AS Fruits1,
'Pineapple' AS Fruits2,
'Grapes' AS Fruits3,
'Melon' AS Fruits4
FOR
XML PATH('Fruits'),
TYPE
)
FOR XML PATH(''),
ROOT('SampleXML')
GO